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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">mateltech</journal-id><journal-title-group><journal-title xml:lang="ru">Известия высших учебных заведений. Материалы электронной техники</journal-title><trans-title-group xml:lang="en"><trans-title>Izvestiya Vysshikh Uchebnykh Zavedenii. Materialy Elektronnoi Tekhniki = Materials of Electronics Engineering</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">1609-3577</issn><issn pub-type="epub">2413-6387</issn><publisher><publisher-name>MISIS</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.17073/1609-3577j.met202404.581</article-id><article-id custom-type="elpub" pub-id-type="custom">mateltech-581</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Физические свойства и методы исследования</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>PHYSICAL CHARACTERISTICS AND THEIR STUDY</subject></subj-group></article-categories><title-group><article-title>Влияние сульфидной пассивации подложки на фотолюминесцентные свойства автоэпитаксиальных слоев InAs</article-title><trans-title-group xml:lang="en"><trans-title>Impact of substrate sulphide passivation on photoluminescent properties of InAs autoepitaxial layers</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0009-0005-6833-2102</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Коляда</surname><given-names>Д. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Kolyada</surname><given-names>D. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>ул. Профессора Попова, д. 5, Санкт-Петербург, 197022</p><p>Коляда Дмитрий Владимирович — младший научный сотрудник</p></bio><bio xml:lang="en"><p>5 Professora Popova Str., St. Petersburg 197022</p><p>Dmitry V. Kolyada — Junior Researcher</p></bio><email xlink:type="simple">kolyada.dima94@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Фирсов</surname><given-names>Д. Д.</given-names></name><name name-style="western" xml:lang="en"><surname>Firsov</surname><given-names>D. D.</given-names></name></name-alternatives><bio xml:lang="ru"><p>ул. Профессора Попова, д. 5, Санкт-Петербург, 197022</p><p>Фирсов Дмитрий Дмитриевич — канд. физ.-мат. наук, доцент кафедры микро- и наноэлектроники</p></bio><bio xml:lang="en"><p>5 Professora Popova Str., St. Petersburg 197022</p><p>Dmitry D. Firsov — Cand. Sci. (Phys.-Math.), Associate Professor of the Department of Micro- and Nanoelectronics</p></bio><email xlink:type="simple">d.d.firsov@gmail.com</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Комков</surname><given-names>О. С.</given-names></name><name name-style="western" xml:lang="en"><surname>Komkov</surname><given-names>O. S.</given-names></name></name-alternatives><bio xml:lang="ru"><p>ул. Профессора Попова, д. 5, Санкт-Петербург, 197022</p><p>Комков Олег Сергеевич — доктор физ.-мат. наук, и.о. заведующего кафедрой микро- и наноэлектроники</p></bio><bio xml:lang="en"><p>5 Professora Popova Str., St. Petersburg 197022</p><p>Oleg S. Komkov — Dr. Sci. (Phys.-Math.), Acting Head of the Department of Micro- and Nanoelectronics</p></bio><email xlink:type="simple">okomkov@yahoo.com</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Соломонов</surname><given-names>А. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Solomonov</surname><given-names>A. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>ул. Профессора Попова, д. 5, Санкт-Петербург, 197022</p><p>Соломонов Александр Васильевич — доктор физ.-мат. наук, профессор</p><p> </p></bio><bio xml:lang="en"><p>5 Professora Popova Str., St. Petersburg 197022</p><p>Alexander V. Solomonov — Dr. Sci. (Phys.-Math.), Professor</p></bio><email xlink:type="simple">alexander.v.solomonov@gmail.com</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Санкт-Петербургский государственный электротехнический университет «ЛЭТИ» им. В.И. Ульянова (Ленина)</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Saint Petersburg Electrotechnical University "LETI"</institution><country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2024</year></pub-date><pub-date pub-type="epub"><day>06</day><month>10</month><year>2024</year></pub-date><volume>27</volume><issue>3</issue><fpage>271</fpage><lpage>277</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Коляда Д.В., Фирсов Д.Д., Комков О.С., Соломонов А.В., 2024</copyright-statement><copyright-year>2024</copyright-year><copyright-holder xml:lang="ru">Коляда Д.В., Фирсов Д.Д., Комков О.С., Соломонов А.В.</copyright-holder><copyright-holder xml:lang="en">Kolyada D.V., Firsov D.D., Komkov O.S., Solomonov A.V.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://met.misis.ru/jour/article/view/581">https://met.misis.ru/jour/article/view/581</self-uri><abstract><p>Методом низкотемпературной инфракрасной фурье-спектроскопии исследованы фотолюминесцентные свойства автоэпитаксиальных слоев арсенида индия. Структуры выращены методом хлоргидридной газофазной эпитаксии на сильнолегированных подложках n+-InAs. Сульфидная пассивация подложек проводилась в одномолярном водном растворе сульфида натрия при комнатной температуре, что приводит к удалению слоя естественного окисла и образованию защищающего поверхность подложки слоя серы. В спектрах фотолюминесценции структур (ФЛ), измеренных на инфракрасном фурье-спектрометре при температуре 8 К, обнаружены три отдельных пика. Пик с энергией 415 мэВ был соотнесен с прямым межзонным переходом в арсениде индия. Мощностная зависимость второго пика, с энергией 400 мэВ, носит сублинейный характер, что позволило отнести его к излучению связанных экситонов. В линии ФЛ третьего пика с максимумом при энергии 388 мэВ наблюдалась тонкая структура с серией близко расположенных пиков, что позволяет отнести данный сигнал к излучению донорно-акцепторных пар. Оценка влияния сульфидизации подложки на качество эпитаксиальных слоев InAs проводилась путем сравнения относительной площади пика ФЛ связанных экситонов для сульфидизированных и не сульфидизированных структур. Показано, что снижение относительной площади пика связанных экситонов после сульфидизации подложки обусловлено уменьшением числа дефектов в автоэпитаксиальных слоях InAs.</p></abstract><trans-abstract xml:lang="en"><p>Photoluminescent properties of indium arsenide autoepitaxial layers have been investigated by low-temperature Fourier-transform infrared spectroscopy. The structures were grown by hydride vapour-phase epitaxy on heavily doped n+-InAs substrates. Sulfide passivation of the substrates was carried out in a unimolar aqueous solution of sodium sulfide at room temperature, which leads to the removal of the natural oxide layer and the formation of a sulfur layer protecting the substrate surface. Three distinct peaks were detected in the photoluminescence spectra of the structures measured on a Fourier-transform infrared spectrometer at 8 K. The peak with an energy of 415 meV corresponds to the direct interband transition in indium arsenide. The power dependence of the second peak, with an energy of 400 meV, has a sublinear character, which allowed us to attribute it to the emission of bound excitons. A structure with a series of closely spaced peaks was observed in the PL line of the third peak with a maximum at an energy of 388 meV, which allows us to attribute this signal to the emission of donor-acceptor pairs. The effect of substrate sulfidisation on the quality of InAs epitaxial layers was assessed by comparing the relative area of the PL peak of bound excitons for sulfidised and non-sulfidised structures. It is shown that the decrease in the relative peak area of bound excitons after substrate sulfidisation is due to a decrease in the number of defects in the InAs autoepitaxial layers. </p></trans-abstract><kwd-group xml:lang="ru"><kwd>арсенид индия</kwd><kwd>автоэпитаксиальный слой</kwd><kwd>фотолюминесценция</kwd><kwd>сульфидизация</kwd><kwd>межзонный переход</kwd><kwd>связанные экситоны</kwd><kwd>донорно-акцепторные пары</kwd><kwd>инфракрасное фотоприемное устройство</kwd></kwd-group><kwd-group xml:lang="en"><kwd>indium arsenide</kwd><kwd>autoepitaxial layer</kwd><kwd>photoluminescence</kwd><kwd>sulfidisation</kwd><kwd>interzone transition</kwd><kwd>bound excitons</kwd><kwd>donor-acceptor pairs</kwd><kwd>infrared photodetector</kwd></kwd-group><funding-group><funding-statement xml:lang="ru">Авторы выражают благодарность А.С. Петрову за предоставленные образцы и П.С. Шилову за помощь в обработке образцов.</funding-statement><funding-statement xml:lang="en">The authors express their gratitude to A.S. Petrov for providing samples  and to P.S. Shilov for assistance in processing the samples.</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Zhijian Shen, Jinshan Yao, Jian Huang, Zhecheng Dai, Luyu Wang, Fengyu Liu, Xinbo Zou, Bo Peng, Weimin Liu, Hong Lu, Baile Chen. High-speed mid-wave infrared uni-traveling carrier photodetector with inductive peaked dewar packaging. Journal of Lightwave Technology. 2023; 42(5): 1504—1510. https://doi.org/10.1109/JLT.2023.3322967</mixed-citation><mixed-citation xml:lang="en">Zhijian Shen, Jinshan Yao, Jian Huang, Zhecheng Dai, Luyu Wang, Fengyu Liu, Xinbo Zou, Bo Peng, Weimin Liu, Hong Lu, Baile Chen. 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