mateltechИзвестия высших учебных заведений. Материалы электронной техникиIzvestiya Vysshikh Uchebnykh Zavedenii. Materialy Elektronnoi Tekhniki = Materials of Electronics Engineering1609-35772413-6387MISIS10.17073/1609-3577j.met202405.582mateltech-582Research ArticleСТАТЬИARTICLESЭлектродные материалы на основе углеродных и металлорганических каркасных структур с встроенными химически активными и функциональными элементами (обзор)Electrode materials based on carbon and metal-organic framework structures with built-in chemically active and functional elementshttps://orcid.org/0000-0002-4865-288XМуратовД. Г.MuratovD. G.

Ленинский просп., д. 29, Москва, 119991;

Ленинский просп., д. 4, стр. 1, Москва, 119049

Муратов Дмитрий Геннадиевич — канд. техн. наук, ведущий научный сотрудник (1), доцент (2)

29 Leninsky Ave., Moscow 119991;

4-1 Leninsky Ave., Moscow 119049

Dmitriy G. Muratov — Cand. Sci. (Eng.), Leading Researcher

muratov@ips.ac.ruhttps://orcid.org/0000-0002-1171-336XСлепцовВ. В.SleptsovV. V.

Волоколамское шоссе, д. 4, Москва, 125993

Слепцов Владимир Владимирович — доктор техн. наук, профессор, зав. кафедрой радиоэлектроники, телекоммуникаций и нанотехнологий

4 Volokolamskoe Highway, Moscow 125993

Vladimir V. Sleptsov — Dr. Sci. (Eng.), Professor, Head of the Department of Radio Electronics, Telecommunications and Nanotechnology

08fraktal@inbox.ruhttps://orcid.org/0000-0002-4973-1328КожитовЛ. В.KozhitovL. V.

Ленинский просп., д. 4, стр. 1, Москва, 119049

Кожитов Лев Васильевич — доктор техн. наук, профессор

4-1 Leninsky Ave., Moscow 119049

Lev V. Kozhitov — Dr. Sci. (Eng.), Professor

kozitov@rambler.ruhttps://orcid.org/0000-0002-9486-2482ЗапороцковаИ. В.ZaporotskovaI. V.

Университетский просп., д. 100, Волгоград, 400062

Запороцкова Ирина Владимировна — доктор физ.-мат. наук, профессор, директор института приоритетных технологий

100 Universitetsky Ave., Volgograd 400062

Irina V. Zaporotskova — Dr. Sci. (Phys.-Math.), Professor, Director of the Institute of Priority Technologies

irinazaporotskova@gmail.comhttps://orcid.org/0000-0003-4657-9305ПопковаА. В.PopkovaA. V.

ул. Железнодорожная, д. 24, Подольск, 142103

Попкова Алёна Васильевна — канд. тех. наук, старший научный сотрудник

24 Zheleznodorozhnaya Str., Podolsk 142103

Alena V. Popkova — Cand. Sci. (Eng.), Senior Researcher

popkova-alena@rambler.ruhttps://orcid.org/0000-0002-0819-6517ДителеваА. О.DitelevaA. O.

Волоколамское шоссе, д. 4, Москва, 125993

Дителева Анна Олеговна — старший преподаватель, кафедра радиоэлектроники, телекоммуникаций и нанотехнологий

4 Volokolamskoe Highway, Moscow 125993

Anna O. Diteleva — Senior Lecturer, Department of Radio Electronics, Telecommunications and Nanotechnology

anna.diteleva@mail.ruhttps://orcid.org/0000-0002-6968-1495КукушкинД. Ю.KukushkinD. Yu.

Волоколамское шоссе, д. 4, Москва, 125993

Кукушкин Дмитрий Юрьевич — канд. техн. наук, доцент, кафедра радиоэлектроники, телекоммуникаций и нанотехнологий

4 Volokolamskoe Highway, Moscow 125993

Dmitry Yu. Kukushkin — Cand. Sci. (Eng.), Associate Professor, Department of Radio Electronics, Telecommunications and Nanotechnology

Skyline34@nxt.ruЦырковР. А.TsyrkovR. A.

Волоколамское шоссе, д. 4, Москва, 125993

Цырков Роман Александрович — ассистент, кафедра радиоэлектроники, телекоммуникации и нанотехнологии

4 Volokolamskoe Highway, Moscow 125993

Roman A. Tsyrkov — Assistant, Department of Radio Electronics, Telecommunications and Nanotechnology

ЗоринА. В.ZorinA. V.

Ленинский просп., д. 4, стр. 1, Москва, 119049

Зорин Артём Викторович — аспирант, кафедра технологий материалов электроники

4-1 Leninsky Ave., Moscow 119049

Artem V. Zorin — Postgraduate Student

m1602075@edu.misis.ruИнститут нефтехимического синтеза им. А.В. Топчиева Российской академии наук; Национальный исследовательский технологический университет «МИСИС»РоссияA.V. Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences; National University of Science and Technology “MISIS”Russian FederationМосковский авиационный институтРоссияMoscow Aviation InstituteRussian FederationНациональный исследовательский технологический университет «МИСИС»РоссияNational University of Science and Technology “MISIS”Russian FederationВолгоградский государственный университетРоссияVolgograd State UniversityRussian FederationАО «НИИ НПО «ЛУЧ»РоссияJSC “Research Institute NPO “LUCH”Russian Federation202426082024273199222Copyright © Муратов Д.Г., Слепцов В.В., Кожитов Л.В., Запороцкова И.В., Попкова А.В., Дителева А.О., Кукушкин Д.Ю., Цырков Р.А., Зорин А.В., 20242024Муратов Д.Г., Слепцов В.В., Кожитов Л.В., Запороцкова И.В., Попкова А.В., Дителева А.О., Кукушкин Д.Ю., Цырков Р.А., Зорин А.В.Muratov D.G., Sleptsov V.V., Kozhitov L.V., Zaporotskova I.V., Popkova A.V., Diteleva A.O., Kukushkin D.Y., Tsyrkov R.A., Zorin A.V.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://met.misis.ru/jour/article/view/582

 работе представлен обзор различных видов углеродных матриц с высокой удельной поверхностью и технологии заполнения их химически активными и вспомогательными материалами. Основное внимание уделено перспективным матрицам на основе металлорганических каркасов (МОК) и на основе серийно выпускаемых рулонных углеродных материалов типа «Бусофит». Рассмотрены их особенности структуры, представлена классификация. Рассмотрены основные методы и подходы к синтезу как самих МОК, так и композиционных материалов на их основе. В качестве одного из вариантов изменения свойств МОК и композиционных материалов на их основе представлен подход, основанный на допировании МОК со структурой ZIF-67 другим металлом. В частности, научным коллективом авторов реализован синтез кобальтовых МОК, в которых Co частично замещен марганцем на стадии синтеза. Помимо этого, использована простая методика синтеза путем соосаждения в водном растворе, но модифицированная ультразвуковым воздействием, которое сокращает продолжительность синтеза. Электрохимические исследования показали, что удельная электрохимическая емкость электродов из пиролизованных МОК с частичным замещением кобальта на марганец значительно выше, чем у материалов без марганца. С увеличением содержания марганца в МОК возрастает как удельная емкость, так и плотность энергии. Допирование МОК Mn позволяет значительно (от 100 до 298 Ф/г при плотности тока 0,25 А/г) улучшить электрохимические характеристики материалов электродов для гибридных суперконденсаторов на их основе. Полученные авторами результаты свидетельствуют о том, что замещение кобальта марганцем является эффективным способом повышения электрохимических характеристик МОК. 

The paper presents an overview of various types of carbon matrices with a high specific surface area and the technology of filling them with chemically active and auxiliary materials. The main attention is paid to promising matrices based on metal-organic frameworks (MOFs) and on commercially available rolled carbon materials such as Busofit. Their structural features are considered and their classification is presented. The main methods and approaches to the synthesis of both MOFs themselves and composite materials based on them are considered.As one of the options for changing the properties of MOFs and composite materials based on them, an approach based on doping MOFs with a ZIF-67 structure with another metal is presented. In particular, the scientific team of authors implemented the synthesis of cobalt MOFs, in which Co is partially replaced by manganese at the synthesis stage. In addition, a simple synthesis technique was used by coprecipitation in an aqueous solution, but modified by ultrasonic exposure, which reduces the duration of the synthesis. Electrochemical studies have shown that the specific electrochemical capacity of electrodes from pyrolyzed MOFs with partial substitution of cobalt with manganese is significantly higher than that of materials without manganese. With an increase in the manganese content in MOFs, both the specific capacity and the energy density increase. Doping MOFs with Mn allows for a significant (from 100 to 298 F/g at a current density of 0.25 A/g) improvement in the electrochemical characteristics of electrode materials for hybrid supercapacitors based on them. The results obtained by the authors indicate that substituting cobalt with manganese is an effective way to improve the electrochemical characteristics of MOFs.

металлорганические каркасыZIF-67органические линкерыионы металловэлектроды для гибридных суперконденсаторовметаллоуглеродные нанокомпозитыпиролизэлектродный материалгибридный конденсаторуглеродная матрицатонкопленочная технологиянанотехнологииmetal-organic frameworksZIF-67organic linkersmetal ionselectrodes for hybrid supercapacitorsmetal-carbon nanocompositespyrolysiselectrode materialhybrid capacitorcarbon matrixthin-film technologynanotechnologyРабота выполнена в рамках государственного задания Минобрнауки России, номер темы FSFF-2023-0008.The work was supported by the Russian Ministry of Science and Higher Education, through state assignment No. FSFF-2023-0008.ReferencesКозадеров О.А. Современные химические источники тока. СПб.: Лань; 2017. 132 с.Козадеров О.А. Современные химические источники тока. СПб.: Лань; 2017. 132 с.Choi J.U., Voronina N., Sun Y.-K., Myung S.-T. 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The authors declare that there are no conflicts of interest present.