Crystallochemical features of simplest and mixed-layered bismuth oxides
https://doi.org/10.17073/1609-3577-2016-4-279-283
Abstract
The family of bismuth ferroelectrics with a layered structure have for more than half a century caused great interest of researchers from theoretical and practical viewpoints. Theoretical interest is due to the specific structure of the compounds with high-temperature blurred ferroelectric transition, while practical one stems from the possibility of obtaining multifunctional materials. This work deals with the crystallochemical analysis of the least−studied species of the family, i.e., the simplest compositions of the “Bi2O3 − second oxide” type and complex precipitation structures, i.e., compounds with the so−called mixed−layered lattice structure.We suggest crystallochemical formulae to describe the compositions of the abovementioned structure types. We expect these formulae to provide for a more focused synthesis of new compounds of the family.
About the Author
V. G. Osipyan
Smolensk State Agrarian Academy
Russian Federation
Valentin G. Osipyan — Cand. Sci. (Eng.).
Russian Federation
Valentin G. Osipyan — Cand. Sci. (Eng.).
10/2 Bol’shaya Sovetskaya Str., Smolensk 214000.
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Review
For citations:
Osipyan V.G. Crystallochemical features of simplest and mixed-layered bismuth oxides. Izvestiya Vysshikh Uchebnykh Zavedenii. Materialy Elektronnoi Tekhniki = Materials of Electronics Engineering. 2016;19(4):279-283. (In Russ.) https://doi.org/10.17073/1609-3577-2016-4-279-283
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