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The effect chemical treatment of the substrate cadmium telluride on the quality of epitaxial structures

https://doi.org/10.17073/1609-3577-2018-1-43-47

Abstract

The etching of wafers of cadmium telluride in aqueous and nonaqueous solutions before the epitaxial process of building structures CdxHg1-xTe and its influence on the surface quality of epitaxial layers. As the etchants investigated 2—20 % solution of bromine in isobutyl alcohol, 5 % solution of bromine in methanol, dimethylsulfoxide, ethylene glycol, solutions of bromine in hydrobromic acid and mixed with glycerin, a saturated solution of potassium dichromate in sulfuric acid. The speed of etching was varied from 0.2 to 9 µm/min. Polishing Set nature of the etching substrate of cadmium telluride in 5 % solution of bromine in i-butanol, the dissolution process is diffusion in nature and is limited by the mass transfer of the reactants in the temperature range of 10—60 °C, depending on the concentration of bromine and the viscosity of the solution. Studied the morphology and surface finish of epitaxial layers of CdxHg1-xTe, depending on the method of etching the original substrate. Found the optimal compositions of etchants for precipitaciones processing of obtaining structures with a height of asperities of the surface at 0.1 atm.

About the Authors

V. V. Paramonov
Kaluga Branch of Bauman Moscow State Technical University
Russian Federation

Victor V. Paramonov: Cand. Sci. (Chim.), Associate Professor 

2 Bazhenova Str, Kaluga 248000



O. V. Novikova
JSC «MeGa Epitech»
Russian Federation

O. V. Novikova: Engineer 

19 2th Akademicheski Proezd, Kaluga 248033



V. G. Kosushkin
Kaluga Branch of Bauman Moscow State Technical University
Russian Federation

Victor G. Kosushkin: Dr. Sci. (Eng.), Professor 

2 Bazhenova Str, Kaluga 248000



References

1. Ponomarenko V. P. Cadmium mercury telluride and the new generation of photoelectronic devices. Physics-Uspekhi, 2003, vol. 46, no. 6, pp. 629—644. DOI: 10.1070/PU2003v046n06ABEH001372

2. Kozhitov L. V., Kosushkin V. G., KrapuhinV. V., Parkhomenko Yu. N. Tekhnologiya materialov mikro- i nanoelektroniki [Materials technology micro- and nanotechnology]. Moscow: MISiS, 2007, 544 p. (In Russ.)

3. Atuchin V. V., Borisov S. V., Magarill S. A., Pervukhina N. V. Crystal structural premises to epitaxial contacts for a series of mercury-containing compounds. J. Crystal Growth, 2011, vol. 318, no. 1, pp. 1125—1128. DOI: 10.1016/j.jcrysgro.2010.08.059

4. Jiang Q., Mullins J. T., Toman J., Hase T. P., Cantwell B. J., Lloyd G., Basu A., Brinkman A. W., Hetero-epitaxial crystal growth of CdTe on GaAs substrates. J. Crystal Growth, 2008, vol. 310, no. 7–9, pp. 1652—1656. DOI: 10.1016/j.jcrysgro.2007.11.171

5. Nouruzi-Khorasani A., Lunn M. A., Jones I. P., Dobson P. S., Williams D. J., Astles M. G. Surface damage of CdTe by mechanical polishing investigated by cross-sectional TEM. J. Crystal Growth, 1990, vol. 102, no. 4, pp. 1069—1073. DOI: 10.1016/00220248(90)90877-N

6. Kosushkin V. G., Kozhitov L. V., Golovatyi Yu. P., Emel’yanov S. G., Chervyakov L. M., Muratov D. G. Modeli i algoritmy resheniya zadach tekhnologii materialov mikro- i nanoelektroniki [Models and algorithms for solving problems of the technology of materials of micro- and nanoelectronics]. Kursk: Yugo-Zap. gos. un-t., 2018, 359 p. (In Russ.)

7. Kol’tgof I. M., Sendel E. B. Kolichestvennyi analiz [Quantitative Analysis]. Moscow: Goschimizdat, 1948, pp. 635—657. (In Russ.)

8. Ivanits’ka V. G., Tomashik Z. F., Tomashik V. M., Feychuk P. I., Moravec P., Franc J. The influence of the CdTe crystallographic orientation on its etching with iodine-separating mixtures Н2О2-HI-С6Н8О7/ethylene glycol. Kondensirovannye sredy i mezhfaznye granitsy, 2007, vol. 9, no. 1, pp. 47—52. (In Russ.). URL: http://www.kcmf.vsu.ru/resources/t_09_1_2007_008.pdf

9. Invention No. 0002542894. Sposob poliruyushchego travitelya dlya tellurida kadmiya rtuti [Polishing etchant method for cadmium mercury telluride]. A. S. Kashuba, E. V. Permikina, 2015. URL: https://edrid.ru/rid/216.013.2ca2.html

10. Invention No. 0002611211. Sposob passivatsii poverkhnosti tellurida kadmiya rtuti [Method for passivation of mercury cadmium telluride surface]. A. S. Kashuba, S. V. Golovin, 2017. URL: https:// edrid.ru/rid/216.013.2ca2.html

11. Invention No. 0002619423. Sposob selektivnogo travitelya dlya tellurida kadmiya rtuti [Method of selective etchant for cadmium telluride mercury]. A. S. Kashuba, E. V. Permikina,P. R. Petrova, 2017.

12. Paramonov V. V., Novikova O. V., Kosushkin V. G. Chemical etching and thermal treatment of cadmium-mercury telluride structures. Nelineinyi mir = Nonlinear World, 2017, vol. 15, no. 4, pp. 64—68. (In Russ.)

13. Pat. 2004130554А (RF). Sposob khimicheskogo travleniya tellurida kadmiya [Method of chemical etching of cadmium telluride]. N. N. Kolesnikov, V. V. Kveder, E. B. Borisenko, D. N. Borisenko,V. K. Gartman, 2006. (In Russ.)

14. Tomashik Z. F., Tomashik V. N., Denisyuk R. A., Chernyuk A. S., Rarenko I. M. Chemical etching of Cd1-xMnxTe solid solution single crystals with iodine solutions in methanol. Russian Journal of Inorganic Chemistry, 2009, vol. 54, no 6, pp. 881—884. DOI: 10.1134/S0036023609060102

15. Pogozheva A. V., Golovin S. V., Lakmanova M. R., Zaharov E. F., Kashuba A. S. Сhemical-mechanical treatment of the cadmium-zinc-telluride surface using the sulfuric acid as an etching agent. Prikladnaya fizika, 2015, no. 5, pp. 80—83. (In Russ.)

16. Vorotyntsev V. M., Skupov V. D. Bazovye tekhnologii mikro- i nanoelektroniki [Basic technologies of micro- and nanoelectronics]. Moscow: Prospekt, 2017, 520 p. (In Russ.)

17. Ivanits’ka V. G., Moravec P., Franc J., Tomashik Z. F., Feychuk P. I., Tomashik V. M., Shcherbak L. P., Mašek K., Höschl P. Chemical etching of CdTe in aqueous solutions of H2O2 - HF - citric acid. J. of Electronic Materials, 2007, vol. 36, no. 8, pp. 1921—1024. DOI: 10.1007/s11664-007-0166-9

18. Gangash P., Milnes A. G. Etching of Cadmium Telluride. J. Electrochem. Soc., 1981, vol. 128, no. 4, pp. 924— 926. DOI: 10.1149/1.2127534


Review

For citations:


Paramonov V.V., Novikova O.V., Kosushkin V.G. The effect chemical treatment of the substrate cadmium telluride on the quality of epitaxial structures. Izvestiya Vysshikh Uchebnykh Zavedenii. Materialy Elektronnoi Tekhniki = Materials of Electronics Engineering. 2018;21(1):43-47. (In Russ.) https://doi.org/10.17073/1609-3577-2018-1-43-47

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