Corrosion of aluminum conductive alloy E-AlMgSi (Aldrey) alloyed by indium
https://doi.org/10.17073/1609-3577-2020-2-151-161
Abstract
The effect of impurities on the electrical resistance of aluminum is well understood. It is known that the conductivity of aluminum is 65.45 % of the conductivity of copper. The tensile strength of aluminum wires is 150—170 MPa, which, with equal conductivity, is about 65 % of the strength of a copper wire. Such strength of aluminum wires is sufficient to support its own weight and may be insufficient when overloaded with snow, ice or wind.
One of the ways to increase the strength of aluminum wires is the use of aluminum alloys having increased strength with a sufficiently high conductivity. One representative of the group of such alloys is the alloy E-AlMgSi (Aldrey). The main hardener of this alloy is the Mg2Si phase, which gives aluminum high mechanical properties.
The paper presents the results of a study of the kinetics of high-temperature oxidation and electrochemical corrosion of indium-doped aluminum conductor alloy E-AlMgSi (Aldrey). Using thermogravimetry, it was shown that indium additives and temperature increase the oxidizability of the E-AlMgSi alloy (Aldrey). In this case, the apparent activation energy of the oxidation of alloys decreases from 120.5 to 91.8 kJ/mol. The oxidation rate of alloys determined by the potentiostatic method in a NaCl electrolyte showed that the corrosion resistance of alloys with indium is 20—30 % higher than that of the original alloy. With increasing concentration of NaCl electrolyte in the electrochemical potentials of the alloys decrease, the corrosion rate increases regardless of their composition.About the Authors
I. N. GanievTajikistan
Izatullo N. Ganiev: Dr. Sci. (Chem.), Professor, Academician of the National Academy of Sciences of Tajikistan, Head of Laboratory
299/2, Sadriddin Ayni Str., Dushanbe 734063, Tajikistan
F. A. Aliev
Tajikistan
Firdavs A. Aliev: Assistant of the Department "Rural construction, hydraulic engineering and geology"
25 Markazi Str., Dangara 735320, Tajikistan
X. O. Odinazoda
Tajikistan
Haydar O. Odinazoda: Dr. Sci. (Eng.), Professor, Corr. Academy of Sciences of the Republic of Tajikistan, Rector of the Tajik Technical University named after M.S. Osimi
10 Radjabov Ave., Dushanbe 734042, Tajikistan
A. M. Safarov
Tajikistan
Ahror M. Safarov: Dr. Sci. (Eng.), Professor, Director of the Institute
299/2, Sadriddin Ayni Str., Dushanbe 734063, Tajikistan
P. Usmonov
Tajikistan
Rakhmazhon Usmonov: Dr. Sci. (Chem.), Chief Researcher, Laboratory of «Hydrocyclic Compounds»
299/2, Sadriddin Ayni Str., Dushanbe 734063, Tajikistan
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Review
For citations:
Ganiev I.N., Aliev F.A., Odinazoda X.O., Safarov A.M., Usmonov P. Corrosion of aluminum conductive alloy E-AlMgSi (Aldrey) alloyed by indium. Izvestiya Vysshikh Uchebnykh Zavedenii. Materialy Elektronnoi Tekhniki = Materials of Electronics Engineering. 2020;23(2):151-161. (In Russ.) https://doi.org/10.17073/1609-3577-2020-2-151-161