Углеродные наноструктуры, содержащие примесные атомы бора: особенности получения, физико-химические свойства и возможности применения
https://doi.org/10.17073/1609-3577-2022-1-64-91
Аннотация
Введение атомов замещения в углеродные нанотрубки – это эффективный способом контроля их физико-химических свойств, позволяющий расширять возможности их практического применения. Одним из наиболее привлекательных материалов для модифицирования углеродных нанотрубок является бор. Однако до настоящего времени не проведено систематизации результатов исследований, связанных с влиянием примесных атомов бора на свойства углеродных нанотрубок, что ослабляет возможность промышленного использования этого наноматериала. В работе рассмотрены наиболее эффективные (из предложенных на сегодня) способы получения углеродных нанотрубок, содержащих примесные атомы бора, проанализированы физико-химические свойства полученных наноматериалов. Кроме того, на основании теоретических и реальных экспериментов дан прогноз возможных областей их применения. Как показал сравнительный анализ разработанных технологий, наиболее эффективным методом является каталитическое осаждение паров из газовой фазы. Также рассмотрены механические, электронные и химические свойства бороуглеродных нанотрубок. Для более полного освещения вопроса о зависимости физико-химических свойств углеродных нанотрубок от концентрации борных примесей проведен модельный эксперимент с применением инструментария квантовой химии, показавший, что между шириной запрещенной зоны и количеством примесных атомов бора присутствует прямая зависимость. Представлены основные направления практического использования боросодержащих углеродных нанотрубок.
Об авторе
С. В. БорознинРоссия
Университетский просп., д. 100, Волгоград, 400062
Борознин Сергей Владимирович — канд. физ.-мат. наук, доцент, заведующий кафедрой судебной экспертизы и физического материаловедения
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Рецензия
Для цитирования:
Борознин С.В. Углеродные наноструктуры, содержащие примесные атомы бора: особенности получения, физико-химические свойства и возможности применения. Известия высших учебных заведений. Материалы электронной техники. 2022;25(1):64-91. https://doi.org/10.17073/1609-3577-2022-1-64-91
For citation:
Boroznin S.V. Carbon nanostructures containing boron impurity atoms: synthesis, physicochemical properties and potential applications. Izvestiya Vysshikh Uchebnykh Zavedenii. Materialy Elektronnoi Tekhniki = Materials of Electronics Engineering. 2022;25(1):64-91. (In Russ.) https://doi.org/10.17073/1609-3577-2022-1-64-91