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Effect of boron impurities of different concentrations on the sensory properties of carbon nanotubes with respect to carbon dioxide

https://doi.org/10.17073/1609-3577j.met202310.605

Abstract

Nanotubes, being one of the most sought after materials in nanotechnology, are finding new areas of application, such as filters for harmful gases. However, in practical applications of nanotubes, it often turns out that, after capturing the analyzed substance, there is no change in their electronic state. This makes it difficult to detect the fact of adsorption of a substance by electronic devices, such as touch sensors. One way to solve this problem could be to modify the surface of carbon nanotubes with various atoms, which leads to the creation of nanotubular heterostructures. One of the most effective substances for carrying out the substitution reaction is boron. It allows the creation of a redistribution of the electron density on the surface of nanotubes without introducing significant changes to the topology of the nanotube surface. This, in turn, leads to a change in the electron-energy structure of the resulting systems and can lead to a more pronounced change in this structure during the sorption of atoms and molecules on the surface of such modified nanotubes. This paper analyzes the effect of boron impurities of different concentrations on the sensory activity of such boron-modified carbon nanotubes towards carbon dioxide to study the possibility of using boron-carbon systems such as a material for high-performance sensors.

About the Authors

S. V. Boroznin
Volgograd State University
Russian Federation

100 Universitetsky Ave., Volgograd 400062

Sergey V. Boroznin — Cand. Sci. (Phys.­-Math.), Associate Professor, Head of the Department of Forensic Science and Physical Materials Science



I. V. Zaporotskova
Volgograd State University
Russian Federation

100 Universitetsky Ave., Volgograd 400062

Irina V. Zaporotskova — Dr. Sci. (Phys.­-Math.), Professor, Director of the Institute of Priority Technologies



P. A. Zaporotskov
Volgograd State University
Russian Federation

100 Universitetsky Ave., Volgograd 400062

Pavel A. Zaporotskov — Cand. Sci. (Phys.­-Math.), Associate Professor of the Department of Forensic Science and Physical Materials Science



N. P. Boroznina
Volgograd State University
Russian Federation

100 Universitetsky Ave., Volgograd 400062

Natalya P. Boroznina — Dr. Sci. (Phys.­-Math.), Professor, Department of Forensic Science and Physical Materials Science



L. V. Kozhitov
National University of Science and Technology “MISIS”
Russian Federation

4­-1 Leninsky Ave., Moscow 119049

Lev V. Kozhitov — Dr. Sci. (Eng.), Professor



A. V. Popkova
JSC “Research Institute NPO “LUCH”
Russian Federation

24 Zheleznodorozhnaya Str., Podolsk 142103

Alena V. Popkova — Cand. Sci. (Eng.), Senior Researcher



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Review

For citations:


Boroznin S.V., Zaporotskova I.V., Zaporotskov P.A., Boroznina N.P., Kozhitov L.V., Popkova A.V. Effect of boron impurities of different concentrations on the sensory properties of carbon nanotubes with respect to carbon dioxide. Izvestiya Vysshikh Uchebnykh Zavedenii. Materialy Elektronnoi Tekhniki = Materials of Electronics Engineering. 2024;27(2):146-153. (In Russ.) https://doi.org/10.17073/1609-3577j.met202310.605

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ISSN 1609-3577 (Print)
ISSN 2413-6387 (Online)